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Preheat oven to 350°.
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Grease and flour a 12 cup Bundt pan.
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Sift together the cake flour, baking powder, and the salt, set aside.
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Cream the sugar and butter until light and fluffy.
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Add the eggs one at a time, beating well after each addition.
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Combine the whiskey and espresso powder in a small measuring cup or bowl, stir to dissolve the powder, if it doesn’t fully dissolve you can briefly warm the mixture in the microwave for a few seconds, be careful not get it more than just barely warm.
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When dissolved, add to the butter mixture. Beat until well combined.
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By hand fold in ½ of the flour mixture following by all of the buttermilk and then the remaining flour mixture alternating with buttermilk.
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Fold in chopped pistachios.
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Spread the batter into the prepared Bundt Pan.
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Bake the cake for 55-60 minutes or until a cake tester when inserted near the center comes out clean. And it is golden brown.
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Let the cake cool for 10 minutes.
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Meanwhile mix together the glaze: in a small bowl or measuring cup mix together the water, ½ cup whiskey, and the powdered sugar.
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When the cake has cooled 10 minutes in the pan invert onto a wire rack over a cookie sheet.
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Immediately pour and brush the glaze over the hot cake, scooping any glaze that falls below back onto the cake until most of the glaze has been absorbed.
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When completely cooled place the cake on a serving platter or stand
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Combine the 1 cup of powdered sugar and the Irish Whiskey. Pour over the cooled cake. Sprinkle with the chopped pistachios.