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Line a 13 x 9 baking pan, preferably with straight sides, with parchment or wax paper.
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Have all the ingredients ready for the bars, as they come together quickly.
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In a large saucepan or Dutch oven, melt 2 tablespoons of the butter over medium heat.
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Add the chopped pecans and cook until the pecans have nicely toasted and browned. Stir them continuously, as they will go from toasted to burn quickly.
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Scrape out the butter and pecans with a spatula and reserve. No need to wash out the pan.
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Add the remaining 4 tablespoons of butter and let the butter melt down and begin to brown, the butter will give off a nutty fragrance, and there will be brown bits of milk solids.
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Immediately add the marshmallows and stir to melt.
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Stir in the bourbon and the vanilla.
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Take off the heat and stir in the rice cereal and the pecans.
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When the cereal has almost been combined, add in the ¾ cup of mini marshmallows.
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Spread the mixture into the prepared pan.
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Using a spatula and a piece of parchment paper, gently press the mixture until the top is even and relatively smooth.
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Let cool completely.